A carregar...
Ce(IV)- and HClO(4)-Promoted Assembly of an Fe(2)(IV)(μ-O)(2) Diamond Core from its Monomeric Fe(IV)=O Precursor at Room Temperature
Diiron(IV)-oxo species are proposed to effect the cleavage of strong C–H bonds by nonheme diiron enzymes such as soluble methane monooxygenase (sMMO) and fatty acid desaturases. However, synthetic mimics of such diiron(IV) oxidants are rare. Herein we report the reaction of (TPA*)Fe(II) (1) (TPA* =...
Na minha lista:
| Publicado no: | Angew Chem Int Ed Engl |
|---|---|
| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2020
|
| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7708462/ https://ncbi.nlm.nih.gov/pubmed/32902902 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202010027 |
| Tags: |
Adicionar Tag
Sem tags, seja o primeiro a adicionar uma tag!
|