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Sc(3+) (or HClO(4)) Activation of a Nonheme Fe(III)–OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene

[Fe(β-BPMCN)(CH(3)CN)(2)](2+) (1, BPMCN = N,N′-bis(pyridyl-2-methyl)-N,N′-dimethyl-trans-1,2-diamino-cyclo-hexane) is a relatively poor catalyst for cyclohexane oxidation by H(2)O(2) and cannot perform benzene hydroxylation. However, addition of Sc(3+) activates the 1/H(2)O(2) reaction mixture to be...

詳細記述

保存先:
書誌詳細
出版年:J Am Chem Soc
主要な著者: Kal, Subhasree, Draksharapu, Apparao, Que, Lawrence
フォーマット: Artigo
言語:Inglês
出版事項: 2018
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC5939927/
https://ncbi.nlm.nih.gov/pubmed/29618199
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b01435
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