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Sc(3+) (or HClO(4)) Activation of a Nonheme Fe(III)–OOH Intermediate for the Rapid Hydroxylation of Cyclohexane and Benzene
[Fe(β-BPMCN)(CH(3)CN)(2)](2+) (1, BPMCN = N,N′-bis(pyridyl-2-methyl)-N,N′-dimethyl-trans-1,2-diamino-cyclo-hexane) is a relatively poor catalyst for cyclohexane oxidation by H(2)O(2) and cannot perform benzene hydroxylation. However, addition of Sc(3+) activates the 1/H(2)O(2) reaction mixture to be...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2018
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5939927/ https://ncbi.nlm.nih.gov/pubmed/29618199 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b01435 |
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