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Ce(IV)- and HClO(4)-Promoted Assembly of an Fe(2)(IV)(μ-O)(2) Diamond Core from its Monomeric Fe(IV)=O Precursor at Room Temperature

Diiron(IV)-oxo species are proposed to effect the cleavage of strong C–H bonds by nonheme diiron enzymes such as soluble methane monooxygenase (sMMO) and fatty acid desaturases. However, synthetic mimics of such diiron(IV) oxidants are rare. Herein we report the reaction of (TPA*)Fe(II) (1) (TPA* =...

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Bibliografiset tiedot
Julkaisussa:Angew Chem Int Ed Engl
Päätekijät: Draksharapu, Apparao, Xu, Shuangning, Que, Lawrence
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2020
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC7708462/
https://ncbi.nlm.nih.gov/pubmed/32902902
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202010027
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