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Ce(IV)- and HClO(4)-Promoted Assembly of an Fe(2)(IV)(μ-O)(2) Diamond Core from its Monomeric Fe(IV)=O Precursor at Room Temperature
Diiron(IV)-oxo species are proposed to effect the cleavage of strong C–H bonds by nonheme diiron enzymes such as soluble methane monooxygenase (sMMO) and fatty acid desaturases. However, synthetic mimics of such diiron(IV) oxidants are rare. Herein we report the reaction of (TPA*)Fe(II) (1) (TPA* =...
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| Publicado en: | Angew Chem Int Ed Engl |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado: |
2020
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| Assuntos: | |
| Acceso en liña: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7708462/ https://ncbi.nlm.nih.gov/pubmed/32902902 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.202010027 |
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