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A synthetic precedent for the [Fe(IV)(2)(μ-O)(2)] diamond core proposed for methane monooxygenase intermediate Q

Intermediate Q, the methane-oxidizing species of soluble methane monooxygenase, is proposed to have an [Fe(IV)(2)(μ-O)(2)] diamond core. In an effort to obtain a synthetic precedent for such a core, bulk electrolysis at 900 mV (versus Fc(+/0)) has been performed in MeCN at −40°C on a valence-delocal...

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Detalhes bibliográficos
Main Authors: Xue, Genqiang, Wang, Dong, De Hont, Raymond, Fiedler, Adam T., Shan, Xiaopeng, Münck, Eckard, Que, Lawrence
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2007
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2409154/
https://ncbi.nlm.nih.gov/pubmed/18093922
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0708516105
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