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Spectroscopic and Theoretical Investigation of a Complex with a [O=Fe(IV)–O–Fe(IV)=O] Core Related to Methane Monooxygenase Intermediate Q
Previous efforts to model the diiron(IV) intermediate Q of soluble methane monooxygenase have led to the synthesis of a diiron(IV) TPA complex, 2, with an O-Fe(IV)-O-Fe(IV)-OH core that has two ferromagnetically coupled S(loc) = 1 sites. Addition of base to 2 at −85 °C elicits its conjugate base 6 w...
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| 主要な著者: | , , , , |
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| フォーマット: | Artigo |
| 言語: | Inglês |
| 出版事項: |
2014
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| 主題: | |
| オンライン・アクセス: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3941033/ https://ncbi.nlm.nih.gov/pubmed/24380398 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja411376u |
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