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Spectroscopic and Theoretical Investigation of a Complex with a [O=Fe(IV)–O–Fe(IV)=O] Core Related to Methane Monooxygenase Intermediate Q

Previous efforts to model the diiron(IV) intermediate Q of soluble methane monooxygenase have led to the synthesis of a diiron(IV) TPA complex, 2, with an O-Fe(IV)-O-Fe(IV)-OH core that has two ferromagnetically coupled S(loc) = 1 sites. Addition of base to 2 at −85 °C elicits its conjugate base 6 w...

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書誌詳細
主要な著者: Stoian, Sebastian A., Xue, Genqiang, Bominaar, Emile L., Que, Lawrence, Münck, Eckard
フォーマット: Artigo
言語:Inglês
出版事項: 2014
主題:
オンライン・アクセス:https://ncbi.nlm.nih.gov/pmc/articles/PMC3941033/
https://ncbi.nlm.nih.gov/pubmed/24380398
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja411376u
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