Mössbauer, EPR and DFT Studies of Synthetic S = ½ Fe(III)-O-Fe(IV)=O Complexes. Superexchange-Mediated Spin Transition at the Fe(IV)=O Site

Previously we have characterized two high-valent complexes [LFe(IV)(µ-O)(2)Fe(III)L], 1, and [LFe(IV)(O)(O)(OH) Fe(IV)L], 4. Addition of hydroxide or fluoride to 1 produces two new complexes, 1-OH and 1-F. EPR and Mössbauer studies show that both complexes have an S = ½ ground state which results fr...

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Detalhes bibliográficos
Main Authors: De Hont, Raymond F., Xue, Genqiang, Hendrich, Michael P., Que, Lawrence, Bominaar, Emile L., Münck, Eckard
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2957120/
https://ncbi.nlm.nih.gov/pubmed/20795646
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic100870v
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