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Spectroscopic Identification of an Fe(III) Center, not Fe(IV), in the Crystalline Sc–O–Fe Adduct Derived from [Fe(IV)(O)(TMC)](2+)
The apparent Sc(3+) adduct of [Fe(IV)(O)-(TMC)](2+) (1, TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized in amounts sufficient to allow its characterization by various spectroscopic techniques. Contrary to the earlier assignment of a +4 oxidation state for the iron...
Shranjeno v:
| izdano v: | J Am Chem Soc |
|---|---|
| Main Authors: | , , , , , , |
| Format: | Artigo |
| Jezik: | Inglês |
| Izdano: |
2015
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| Teme: | |
| Online dostop: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4939224/ https://ncbi.nlm.nih.gov/pubmed/25743366 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00535 |
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