Spectroscopic Identification of an Fe(III) Center, not Fe(IV), in the Crystalline Sc–O–Fe Adduct Derived from [Fe(IV)(O)(TMC)](2+)

The apparent Sc(3+) adduct of [Fe(IV)(O)-(TMC)](2+) (1, TMC = 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane) has been synthesized in amounts sufficient to allow its characterization by various spectroscopic techniques. Contrary to the earlier assignment of a +4 oxidation state for the iron...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Prakash, Jai, Rohde, Gregory T., Meier, Katlyn K., Jasniewski, Andrew J., Van Heuvelen, Katherine M., Münck, Eckard, Que, Lawrence
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
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Article
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC4939224/
https://ncbi.nlm.nih.gov/pubmed/25743366
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b00535
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