טוען...
Characterization of a High-Spin Nonheme Fe(III)–OOH Intermediate and Its Quantitative Conversion to an Fe(IV)=O Complex
We have generated a high-spin Fe(III)–OOH complex supported by tetramethylcyclam via protonation of its conjugate base and characterized it in detail by various spectroscopic methods. This Fe(III)–OOH species converts quantitatively to an Fe(IV)=O complex via O–O bond cleavage, which represents the...
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| Main Authors: | , , , , , , |
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| פורמט: | Artigo |
| שפה: | Inglês |
| יצא לאור: |
2011
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| נושאים: | |
| גישה מקוונת: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3097042/ https://ncbi.nlm.nih.gov/pubmed/21517091 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja111742z |
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