Characterization of a High-Spin Nonheme Fe(III)–OOH Intermediate and Its Quantitative Conversion to an Fe(IV)=O Complex

We have generated a high-spin Fe(III)–OOH complex supported by tetramethylcyclam via protonation of its conjugate base and characterized it in detail by various spectroscopic methods. This Fe(III)–OOH species converts quantitatively to an Fe(IV)=O complex via O–O bond cleavage, which represents the...

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Main Authors: Li, Feifei, Meier, Katlyn K., Cranswick, Matthew A., Chakrabarti, Mrinmoy, Van Heuvelen, Katherine M., Münck, Eckard, Que, Lawrence
Formato: Artigo
Idioma:Inglês
Publicado: 2011
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Article
Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC3097042/
https://ncbi.nlm.nih.gov/pubmed/21517091
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja111742z
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