Kinetic Analysis of the Conversion of Nonheme Alkylperoxoiron(III) Species to Iron(IV) Complexes

Low-spin mononuclear alkylperoxoiron(III) complexes decompose by peroxide O-O bond homolysis to form iron(IV) species. We examined the kinetics of previously reported homolysis reactions for alkylperoxoiron(III) intermediates supported by TPA (tris-(2-pyridylmethyl)amine) in CH(3)CN solution and pro...

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Autores principales: Jensen, Michael P., Payeras, Antoni Mairata i, Fiedler, Adam T., Costas, Miquel, Kaizer, József, Stubna, Audria, Münck, Eckard, Que, Lawrence
Formato: Artigo
Lenguaje:Inglês
Publicado: 2007
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2526350/
https://ncbi.nlm.nih.gov/pubmed/17326618
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic0607787
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