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Kinetic Analysis of the Conversion of Nonheme Alkylperoxoiron(III) Species to Iron(IV) Complexes
Low-spin mononuclear alkylperoxoiron(III) complexes decompose by peroxide O-O bond homolysis to form iron(IV) species. We examined the kinetics of previously reported homolysis reactions for alkylperoxoiron(III) intermediates supported by TPA (tris-(2-pyridylmethyl)amine) in CH(3)CN solution and pro...
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| Main Authors: | , , , , , , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2007
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2526350/ https://ncbi.nlm.nih.gov/pubmed/17326618 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic0607787 |
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