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A Diiron(IV) Complex that Cleaves Strong C-H and O-H Bonds

The controlled cleavage of strong C-H bonds like those of methane poses a significant challenge for chemists. In nature methane is oxidized to methanol by soluble methane monooxygenase via a diiron(IV) intermediate called Q. To model the chemistry of MMO-Q, an oxo-bridged diiron(IV) complex has been...

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Hlavní autoři: Wang, Dong, Farquhar, Erik R., Stubna, Audria, Münck, Eckard, Que, Lawrence
Médium: Artigo
Jazyk:Inglês
Vydáno: 2009
Témata:
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2744316/
https://ncbi.nlm.nih.gov/pubmed/19885382
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1038/nchem.162
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