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An Fe(IV) [Image: see text] O complex of a tetradentate tripodal nonheme ligand
The reaction of [Fe(II)(tris(2-pyridylmethyl)amine, TPA)(NCCH(3))(2)](2+) with 1 equiv. peracetic acid in CH(3)CN at −40°C results in the nearly quantitative formation of a pale green intermediate with λ(max) at 724 nm (ɛ ≈ 300 M(−1)⋅cm(−1)) formulated as [Fe(IV)(O)(TPA)](2+) by a combination of spe...
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| Главные авторы: | , , , , , , , , |
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| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
National Academy of Sciences
2003
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC152979/ https://ncbi.nlm.nih.gov/pubmed/12644707 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0636830100 |
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