An Fe(IV) [Image: see text] O complex of a tetradentate tripodal nonheme ligand

The reaction of [Fe(II)(tris(2-pyridylmethyl)amine, TPA)(NCCH(3))(2)](2+) with 1 equiv. peracetic acid in CH(3)CN at −40°C results in the nearly quantitative formation of a pale green intermediate with λ(max) at 724 nm (ɛ ≈ 300 M(−1)⋅cm(−1)) formulated as [Fe(IV)(O)(TPA)](2+) by a combination of spe...

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Detalhes bibliográficos
Main Authors: Lim, Mi Hee, Rohde, Jan-Uwe, Stubna, Audria, Bukowski, Michael R., Costas, Miquel, Ho, Raymond Y. N., Münck, Eckard, Nam, Wonwoo, Que, Lawrence
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2003
Assuntos:
Physical Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC152979/
https://ncbi.nlm.nih.gov/pubmed/12644707
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0636830100
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