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Axial Ligand Effects on the Geometric and Electronic Structures of Nonheme Oxoiron(IV) Complexes
A series of complexes [Fe(IV)(O)(TMC)(X)](+) (where X = OH(−), CF(3)CO(2)(−), N(3)(−), NCS(−), NCO(−), and CN(−)) were obtained by treatment of the well characterized nonheme oxoiron(IV) complex [Fe(IV)(O)(TMC)(NCMe)](2+) (TMC = tetramethylcyclam) with the appropriate NR(4)X salts. Because of the to...
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| Huvudupphovsmän: | , , , , , , , , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2008
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2574688/ https://ncbi.nlm.nih.gov/pubmed/18712873 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8022576 |
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