Axial Ligand Effects on the Geometric and Electronic Structures of Nonheme Oxoiron(IV) Complexes

A series of complexes [Fe(IV)(O)(TMC)(X)](+) (where X = OH(−), CF(3)CO(2)(−), N(3)(−), NCS(−), NCO(−), and CN(−)) were obtained by treatment of the well characterized nonheme oxoiron(IV) complex [Fe(IV)(O)(TMC)(NCMe)](2+) (TMC = tetramethylcyclam) with the appropriate NR(4)X salts. Because of the to...

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Autores principales: Jackson, Timothy A., Rohde, Jan-Uwe, Seo, Mi Sook, Sastri, Chivukula V., DeHont, Raymond, Ohta, Takehiro, Kitagawa, Teizo, Münck, Eckard, Nam, Wonwoo, Que, Lawrence
Formato: Artigo
Lenguaje:Inglês
Publicado: 2008
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Article
Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC2574688/
https://ncbi.nlm.nih.gov/pubmed/18712873
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja8022576
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