Axial ligand tuning of a nonheme iron(IV)–oxo unit for hydrogen atom abstraction

The reactivities of mononuclear nonheme iron(IV)–oxo complexes bearing different axial ligands, [Fe(IV)(O)(TMC)(X)](n+) [where TMC is 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane and X is NCCH(3) (1-NCCH(3)), CF(3)COO(−) (1-OOCCF(3)), or N(3)(−) (1-N(3))], and [Fe(IV)(O)(TMCS)](+) (1′-SR)...

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Hlavní autoři: Sastri, Chivukula V., Lee, Jimin, Oh, Kyungeun, Lee, Yoon Jin, Lee, Junghyun, Jackson, Timothy A., Ray, Kallol, Hirao, Hajime, Shin, Woonsup, Halfen, Jason A., Kim, Jinheung, Que, Lawrence, Shaik, Sason, Nam, Wonwoo
Médium: Artigo
Jazyk:Inglês
Vydáno: National Academy of Sciences 2007
Témata:
Physical Sciences
On-line přístup:https://ncbi.nlm.nih.gov/pmc/articles/PMC2148264/
https://ncbi.nlm.nih.gov/pubmed/18048327
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0709471104
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