Axial ligand tuning of a nonheme iron(IV)–oxo unit for hydrogen atom abstraction

The reactivities of mononuclear nonheme iron(IV)–oxo complexes bearing different axial ligands, [Fe(IV)(O)(TMC)(X)](n+) [where TMC is 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane and X is NCCH(3) (1-NCCH(3)), CF(3)COO(−) (1-OOCCF(3)), or N(3)(−) (1-N(3))], and [Fe(IV)(O)(TMCS)](+) (1′-SR)...

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Detalhes bibliográficos
Main Authors: Sastri, Chivukula V., Lee, Jimin, Oh, Kyungeun, Lee, Yoon Jin, Lee, Junghyun, Jackson, Timothy A., Ray, Kallol, Hirao, Hajime, Shin, Woonsup, Halfen, Jason A., Kim, Jinheung, Que, Lawrence, Shaik, Sason, Nam, Wonwoo
Formato: Artigo
Idioma:Inglês
Publicado em: National Academy of Sciences 2007
Assuntos:
Physical Sciences
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC2148264/
https://ncbi.nlm.nih.gov/pubmed/18048327
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0709471104
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