Axial ligand tuning of a nonheme iron(IV)–oxo unit for hydrogen atom abstraction

The reactivities of mononuclear nonheme iron(IV)–oxo complexes bearing different axial ligands, [Fe(IV)(O)(TMC)(X)](n+) [where TMC is 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane and X is NCCH(3) (1-NCCH(3)), CF(3)COO(−) (1-OOCCF(3)), or N(3)(−) (1-N(3))], and [Fe(IV)(O)(TMCS)](+) (1′-SR)...

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Autors principals: Sastri, Chivukula V., Lee, Jimin, Oh, Kyungeun, Lee, Yoon Jin, Lee, Junghyun, Jackson, Timothy A., Ray, Kallol, Hirao, Hajime, Shin, Woonsup, Halfen, Jason A., Kim, Jinheung, Que, Lawrence, Shaik, Sason, Nam, Wonwoo
Format: Artigo
Idioma:Inglês
Publicat: National Academy of Sciences 2007
Matèries:
Physical Sciences
Accés en línia:https://ncbi.nlm.nih.gov/pmc/articles/PMC2148264/
https://ncbi.nlm.nih.gov/pubmed/18048327
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0709471104
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