Axial ligand tuning of a nonheme iron(IV)–oxo unit for hydrogen atom abstraction

The reactivities of mononuclear nonheme iron(IV)–oxo complexes bearing different axial ligands, [Fe(IV)(O)(TMC)(X)](n+) [where TMC is 1,4,8,11-tetramethyl-1,4,8,11-tetraazacyclotetradecane and X is NCCH(3) (1-NCCH(3)), CF(3)COO(−) (1-OOCCF(3)), or N(3)(−) (1-N(3))], and [Fe(IV)(O)(TMCS)](+) (1′-SR)...

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Bibliografische gegevens
Hoofdauteurs: Sastri, Chivukula V., Lee, Jimin, Oh, Kyungeun, Lee, Yoon Jin, Lee, Junghyun, Jackson, Timothy A., Ray, Kallol, Hirao, Hajime, Shin, Woonsup, Halfen, Jason A., Kim, Jinheung, Que, Lawrence, Shaik, Sason, Nam, Wonwoo
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: National Academy of Sciences 2007
Onderwerpen:
Physical Sciences
Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC2148264/
https://ncbi.nlm.nih.gov/pubmed/18048327
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0709471104
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