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Tuning the reactivity of mononuclear nonheme manganese(iv)-oxo complexes by triflic acid
Triflic acid (HOTf)-bound nonheme Mn(iv)-oxo complexes, [(L)Mn(IV)(O)](2+)–(HOTf)(2) (L = N4Py and Bn-TPEN; N4Py = N,N-bis(2-pyridylmethyl)-N-bis(2-pyridyl)methylamine and Bn-TPEN = N-benzyl-N,N′,N′-tris(2-pyridylmethyl)ethane-1,2-diamine), were synthesized by adding HOTf to the solutions of the [(L...
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| Publicado no: | Chem Sci |
|---|---|
| Main Authors: | , , , , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
Royal Society of Chemistry
2015
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4486364/ https://ncbi.nlm.nih.gov/pubmed/26146538 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1039/c5sc00535c |
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