Spectroscopic Characterization and Reactivity Studies of a Mononuclear Nonheme Mn(III)–Hydroperoxo Complex

[Image: see text] We report the first example of a mononuclear nonheme manganese(III)–hydroperoxo complex derived from protonation of an isolated manganese(III)–peroxo complex bearing an N-tetramethylated cyclam (TMC) ligand, [Mn(III)(TMC)(OOH)](2+). The Mn(III)-hydroperoxo intermediate is character...

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Main Authors: So, Hee, Park, Young Jun, Cho, Kyung-Bin, Lee, Yong-Min, Seo, Mi Sook, Cho, Jaeheung, Sarangi, Ritimukta, Nam, Wonwoo
Format: Artigo
Jezik:Inglês
Izdano: American Chemical Society 2014
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC4156864/
https://ncbi.nlm.nih.gov/pubmed/25116698
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja506275q
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