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Spectroscopic Characterization and Reactivity Studies of a Mononuclear Nonheme Mn(III)–Hydroperoxo Complex
[Image: see text] We report the first example of a mononuclear nonheme manganese(III)–hydroperoxo complex derived from protonation of an isolated manganese(III)–peroxo complex bearing an N-tetramethylated cyclam (TMC) ligand, [Mn(III)(TMC)(OOH)](2+). The Mn(III)-hydroperoxo intermediate is character...
में बचाया:
| मुख्य लेखकों: | , , , , , , , |
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| स्वरूप: | Artigo |
| भाषा: | Inglês |
| प्रकाशित: |
American Chemical
Society
2014
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| ऑनलाइन पहुंच: | https://ncbi.nlm.nih.gov/pmc/articles/PMC4156864/ https://ncbi.nlm.nih.gov/pubmed/25116698 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja506275q |
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