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Trapping and spectroscopic characterization of an Fe(III)-superoxo intermediate from a nonheme mononuclear iron-containing enzyme
[Image: see text] intermediates are well known in heme enzymes, but none have been characterized in the nonheme mononuclear Fe(II) enzyme family. Many steps in the O(2) activation and reaction cycle of Fe(II)-containing homoprotocatechuate 2,3-dioxygenase are made detectable by using the alternative...
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| Main Authors: | , , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
National Academy of Sciences
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2947897/ https://ncbi.nlm.nih.gov/pubmed/20837547 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1010015107 |
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