Trapping and spectroscopic characterization of an Fe(III)-superoxo intermediate from a nonheme mononuclear iron-containing enzyme

[Image: see text] intermediates are well known in heme enzymes, but none have been characterized in the nonheme mononuclear Fe(II) enzyme family. Many steps in the O(2) activation and reaction cycle of Fe(II)-containing homoprotocatechuate 2,3-dioxygenase are made detectable by using the alternative...

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Detaylı Bibliyografya
Asıl Yazarlar: Mbughuni, Michael M., Chakrabarti, Mrinmoy, Hayden, Joshua A., Bominaar, Emile L., Hendrich, Michael P., Münck, Eckard, Lipscomb, John D.
Materyal Türü: Artigo
Dil:Inglês
Baskı/Yayın Bilgisi: National Academy of Sciences 2010
Konular:
Physical Sciences
Online Erişim:https://ncbi.nlm.nih.gov/pmc/articles/PMC2947897/
https://ncbi.nlm.nih.gov/pubmed/20837547
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.1010015107
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