Oxygen Activation at Mononuclear Nonheme Iron Centers: A Superoxo Perspective

Dioxygen activation by iron enzymes is responsible for many metabolically important transformations in biology. Often a high-valent iron-oxo oxidant is proposed to form upon dioxygen activation at a mononuclear nonheme iron center, presumably via intervening iron-superoxo and iron-peroxo species. Wh...

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Main Authors: Mukherjee, Anusree, Cranswick, Matthew A., Chakraborti, Mrinmoy, Paine, Tapan K., Fujisawa, Kiyoshi, Münck, Eckard, Que, Lawrence
Format: Artigo
Jezik:Inglês
Izdano: 2010
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Article
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC2864595/
https://ncbi.nlm.nih.gov/pubmed/20380464
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic901891n
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