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Oxygen Activation at Mononuclear Nonheme Iron Centers: A Superoxo Perspective
Dioxygen activation by iron enzymes is responsible for many metabolically important transformations in biology. Often a high-valent iron-oxo oxidant is proposed to form upon dioxygen activation at a mononuclear nonheme iron center, presumably via intervening iron-superoxo and iron-peroxo species. Wh...
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| Main Authors: | , , , , , , |
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| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2010
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2864595/ https://ncbi.nlm.nih.gov/pubmed/20380464 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ic901891n |
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