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Substrate-Triggered Activation of a Synthetic [Fe(2)(μ-O)(2)] Diamond Core for C–H Bond Cleavage
An [Fe(IV)(2)(μ-O)(2)] diamond core structure has been postulated for intermediate Q of soluble methane monooxygenase (sMMO-Q), the oxidant responsible for cleaving the strong C–H bond of methane and its hydroxylation. By extension, analogous species may be involved in the mechanisms of related diir...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2011
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3192255/ https://ncbi.nlm.nih.gov/pubmed/21899336 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja207131g |
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