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Substrate-Triggered Activation of a Synthetic [Fe(2)(μ-O)(2)] Diamond Core for C–H Bond Cleavage

An [Fe(IV)(2)(μ-O)(2)] diamond core structure has been postulated for intermediate Q of soluble methane monooxygenase (sMMO-Q), the oxidant responsible for cleaving the strong C–H bond of methane and its hydroxylation. By extension, analogous species may be involved in the mechanisms of related diir...

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Autores principales: Xue, Genqiang, Pokutsa, Alexander, Que, Lawrence
Formato: Artigo
Lenguaje:Inglês
Publicado: 2011
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Acceso en línea:https://ncbi.nlm.nih.gov/pmc/articles/PMC3192255/
https://ncbi.nlm.nih.gov/pubmed/21899336
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja207131g
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