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A synthetic precedent for the [Fe(IV)(2)(μ-O)(2)] diamond core proposed for methane monooxygenase intermediate Q
Intermediate Q, the methane-oxidizing species of soluble methane monooxygenase, is proposed to have an [Fe(IV)(2)(μ-O)(2)] diamond core. In an effort to obtain a synthetic precedent for such a core, bulk electrolysis at 900 mV (versus Fc(+/0)) has been performed in MeCN at −40°C on a valence-delocal...
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| Huvudupphovsmän: | , , , , , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
National Academy of Sciences
2007
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2409154/ https://ncbi.nlm.nih.gov/pubmed/18093922 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0708516105 |
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