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Insights into the P-to-Q conversion in the catalytic cycle of methane monooxygenase from a synthetic model system
For the catalytic cycle of soluble methane monooxygenase (sMMO), it has been proposed that cleavage of the O–O bond in the (μ-peroxo)diiron(III) intermediate P gives rise to the diiron(IV) intermediate Q with an Fe(2)(μ–O)(2) diamond core, which oxidizes methane to methanol. As a model for this conv...
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| Autors principals: | , , , , |
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| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
National Academy of Sciences
2008
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2634879/ https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0808512105 |
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