Insights into the P-to-Q conversion in the catalytic cycle of methane monooxygenase from a synthetic model system

For the catalytic cycle of soluble methane monooxygenase (sMMO), it has been proposed that cleavage of the O–O bond in the (μ-peroxo)diiron(III) intermediate P gives rise to the diiron(IV) intermediate Q with an Fe(2)(μ–O)(2) diamond core, which oxidizes methane to methanol. As a model for this conv...

Full description

Saved in:
Bibliographic Details
Main Authors: Xue, Genqiang, Fiedler, Adam T., Martinho, Marlène, Münck, Eckard, Que, Lawrence
Format: Artigo
Language:Inglês
Published: National Academy of Sciences 2008
Subjects:
Physical Sciences
Online Access:https://ncbi.nlm.nih.gov/pmc/articles/PMC2634879/
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1073/pnas.0808512105
Tags: Add Tag
No Tags, Be the first to tag this record!

Similar Items