Spectroscopic and Reactivity Comparisons of a Pair of bTAML Complexes with Fe(V)=O and Fe(IV)=O Units

In this report we compare the geometric and electronic structures and reactivities of [Fe(V)(O)](−) and [Fe(IV)(O)](2−) species supported by the same ancillary nonheme biuret tetraamido macrocyclic ligand (bTAML). Resonance Raman studies show that the Fe=O vibration of the [Fe(IV)(O)](2−) complex 2...

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Publié dans:Inorg Chem
Auteurs principaux: Pattanayak, Santanu, Jasniewski, Andrew J., Rana, Atanu, Draksharapu, Apparao, Singh, Kundan K., Weitz, Andrew, Hendrich, Michael, Que, Lawrence, Dey, Abhishek, Gupta, Sayam Sen
Format: Artigo
Langue:Inglês
Publié: 2017
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Article
Accès en ligne:https://ncbi.nlm.nih.gov/pmc/articles/PMC5908480/
https://ncbi.nlm.nih.gov/pubmed/28481521
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.7b00448
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