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Activation of Dioxygen by a TAML Activator in Reverse Micelles: Characterization of an Fe(III)Fe(IV) Dimer and Associated Catalytic Chemistry

Iron TAML activators of peroxides are functional catalase-peroxidase mimics. Switching from hydrogen peroxide (H(2)O(2)) to dioxygen (O(2)) as the primary oxidant was achieved by using a system of reverse micelles of Aerosol OT (AOT) in n-octane. Hydrophilic TAML activators are localized in the aque...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Tang, Liang L., Gunderson, William A., Weitz, Andrew C., Hendrich, Michael P., Ryabov, Alexander D., Collins, Terrence J.
Formato: Artigo
Idioma:Inglês
Publicado em: 2015
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5286568/
https://ncbi.nlm.nih.gov/pubmed/26161504
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05229
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