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A “Beheaded” TAML Activator: A Compromised Catalyst that Emphasizes the Linearity between Catalytic Activity and pK(a)
Studies of the new tetra-amido macrocyclic ligand (TAML) activator [Fe(III){(Me(2)CNCOCMe(2)NCO)(2)CMe(2)}OH(2)](−) (4) in water in the pH range of 2–13 suggest its pseudo-octahedral geometry with two nonequivalent axial H(2)O ligands and revealed (i) the anticipated basic drift of the first pK(a) o...
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| Опубликовано в: : | Inorg Chem |
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| Главные авторы: | , , , , , |
| Формат: | Artigo |
| Язык: | Inglês |
| Опубликовано: |
2016
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| Предметы: | |
| Online-ссылка: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5479581/ https://ncbi.nlm.nih.gov/pubmed/27934426 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.inorgchem.6b01988 |
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