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Activation of Dioxygen by a TAML Activator in Reverse Micelles: Characterization of an Fe(III)Fe(IV) Dimer and Associated Catalytic Chemistry
Iron TAML activators of peroxides are functional catalase-peroxidase mimics. Switching from hydrogen peroxide (H(2)O(2)) to dioxygen (O(2)) as the primary oxidant was achieved by using a system of reverse micelles of Aerosol OT (AOT) in n-octane. Hydrophilic TAML activators are localized in the aque...
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| Udgivet i: | J Am Chem Soc |
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| Main Authors: | , , , , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2015
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5286568/ https://ncbi.nlm.nih.gov/pubmed/26161504 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.5b05229 |
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