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Facile and reversible formation of Fe(III)–O–Ce(IV) adducts from nonheme oxoiron(IV) complexes and Ce(III)
CAN or Ce(IV)(NH(4))(2)(NO(3))(6) is often used in artificial water oxidation and generally considered to be an outer-sphere oxidant. Herein we report the spectroscopic and crystallographic characterization of [(N4Py)Fe(III)–O–Ce(IV)(OH(2))(NO(3))(4)](+) (3), a complex obtained from the reaction of...
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| Publicat a: | Angew Chem Int Ed Engl |
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| Autors principals: | , , , |
| Format: | Artigo |
| Idioma: | Inglês |
| Publicat: |
2017
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| Matèries: | |
| Accés en línia: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5598155/ https://ncbi.nlm.nih.gov/pubmed/28598024 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201704322 |
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