Facile Conversion of syn‐[Fe(IV)(O)(TMC)](2+) into the anti Isomer via Meunier's Oxo–Hydroxo Tautomerism Mechanism

The syn and anti isomers of [Fe(IV)(O)(TMC)](2+) (TMC=tetramethylcyclam) represent the first isolated pair of synthetic non‐heme oxoiron(IV) complexes with identical ligand topology, differing only in the position of the oxo unit bound to the iron center. Both isomers have previously been characteri...

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Foilsithe in:Angew Chem Int Ed Engl
Main Authors: Prakash, Jai, Sheng, Yuan, Draksharapu, Apparao, Klein, Johannes E. M. N., Cramer, Christopher J., Que, Lawrence
Formáid: Artigo
Teanga:Inglês
Foilsithe: John Wiley and Sons Inc. 2019
Ábhair:
Communications
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC6470793/
https://ncbi.nlm.nih.gov/pubmed/30556289
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1002/anie.201811454
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