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Catalytic, Enantioselective 1,2-Difluorination of Cinnamamides
We report the enantio- and diastereoselective synthesis of 1,2-difluorides via chiral aryl iodide-catalyzed difluorination of cinnamamides. The method uses HF-pyridine as a fluoride source and mCPBA as a stoichiometric oxidant to turn over catalyst, and affords compounds containing vicinal, fluoride...
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| Udgivet i: | Org Lett |
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| Main Authors: | , , |
| Format: | Artigo |
| Sprog: | Inglês |
| Udgivet: |
2019
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| Fag: | |
| Online adgang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7330813/ https://ncbi.nlm.nih.gov/pubmed/30963766 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/acs.orglett.9b00938 |
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