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Catalytic, Asymmetric Difluorination of Alkenes to Generate Difluoromethylated Stereocenters

Difluoromethyl groups possess specific steric and electronic properties that invite their use as chemically inert surrogates of alcohols, thiols, and other polar functional groups important in a wide assortment of molecular recognition processes. We report here a method for the catalytic, asymmetric...

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Detalhes bibliográficos
Publicado no:Science
Main Authors: Banik, Steven M., Medley, Jonathan William, Jacobsen, Eric N.
Formato: Artigo
Idioma:Inglês
Publicado em: 2016
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC5096785/
https://ncbi.nlm.nih.gov/pubmed/27365443
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaf8078
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