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Catalytic, Asymmetric Difluorination of Alkenes to Generate Difluoromethylated Stereocenters
Difluoromethyl groups possess specific steric and electronic properties that invite their use as chemically inert surrogates of alcohols, thiols, and other polar functional groups important in a wide assortment of molecular recognition processes. We report here a method for the catalytic, asymmetric...
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| Publicado no: | Science |
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| Main Authors: | , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2016
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5096785/ https://ncbi.nlm.nih.gov/pubmed/27365443 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1126/science.aaf8078 |
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