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Catalytic Diastereo- and Enantioselective Fluoroamination of Alkenes
The stereoselective synthesis of syn-β-fluoroaziridine building blocks via chiral aryl iodide-catalyzed fluorination of allylic amines is reported. The method employs HF-pyridine as a nucleophilic fluoride source together with mCPBA as a stoichiometric oxidant, and affords access to arylethylamine d...
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| Publicado no: | J Am Chem Soc |
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| Main Authors: | , , , |
| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2018
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5902804/ https://ncbi.nlm.nih.gov/pubmed/29583001 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.8b02143 |
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