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Enantioselective, Catalytic Fluorolactonization Reactions with a Nucleophilic Fluoride Source
The enantioselective synthesis of 4-fluoroisochromanones via chiral aryl iodide-catalyzed fluorolactonization is reported. This methodology uses HF•pyridine as a nucleophilic fluoride source with a peracid stoichiometric oxidant, and provides access to lactones containing fluorine-bearing stereogeni...
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| Veröffentlicht in: | J Am Chem Soc |
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| Hauptverfasser: | , , |
| Format: | Artigo |
| Sprache: | Inglês |
| Veröffentlicht: |
2016
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| Schlagworte: | |
| Online Zugang: | https://ncbi.nlm.nih.gov/pmc/articles/PMC5382122/ https://ncbi.nlm.nih.gov/pubmed/27709922 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.6b09499 |
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