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Weak Brønsted Acid–Thiourea Co-Catalysis: Enantioselective, Catalytic Protio-Pictet–Spengler Reactions

[Image: see text] The development of one-pot imine formation and asymmetric Pictet–Spengler reactions co-catalyzed by a chiral thiourea and benzoic acid is described. Optically active tetrahydro-β-carbolines, ubiquitous structural motifs in biologically active natural products, are obtained in high...

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Main Authors: Klausen, Rebekka S., Jacobsen, Eric N.
Formato: Artigo
Idioma:Inglês
Publicado: 2009
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC2664157/
https://ncbi.nlm.nih.gov/pubmed/19178157
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ol802887h
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