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Catalytic Enantioselective Synthesis of Difluorinated Alkyl Bromides
We report an iodoarene-catalyzed enantioselective synthesis of β,β-difluoroalkyl halide building blocks. The transformation involves an oxidative rearrangement of α-bromostyrenes, utilizing HF–pyridine as the fluoride source and m-CPBA as the stoichiometric oxidant. A catalyst decomposition pathway...
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| Publicado en: | J Am Chem Soc |
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| Autores principales: | , , , , |
| Formato: | Artigo |
| Lenguaje: | Inglês |
| Publicado: |
2020
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| Materias: | |
| Acceso en línea: | https://ncbi.nlm.nih.gov/pmc/articles/PMC7537710/ https://ncbi.nlm.nih.gov/pubmed/32799536 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.0c07043 |
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