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Enantioselective Catalytic α-Alkylation of Aldehydes via an S(N)1 Pathway
[Image: see text] Primary aminothiourea derivatives are shown to catalyze enantioselective alkylation of α-arylpriopionaldehdyes with diarylbromomethane. Evidence for a stepwise, S(N)1 mechanism in the substitution reaction induced by anion binding to the catalyst is provided by catalyst structure-a...
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| Huvudupphovsmän: | , , |
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| Materialtyp: | Artigo |
| Språk: | Inglês |
| Publicerad: |
2010
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| Ämnen: | |
| Länkar: | https://ncbi.nlm.nih.gov/pmc/articles/PMC2909636/ https://ncbi.nlm.nih.gov/pubmed/20568761 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja103618r |
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