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Enantioselective α-Benzylation of Aldehydes via Photoredox Organocatalysis

The first enantioselective aldehyde α-benzylation using electron-deficient aryl and heteroaryl substrates has been accomplished. The productive merger of a chiral imidazolidinone organocatalyst and a commercially available iridium photoredox catalyst in the presence of household fluorescent light di...

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Detalhes bibliográficos
Main Authors: Shih, Hui-Wen, Vander Wal, Mark N., Grange, Rebecca L., MacMillan, David W. C.
Formato: Artigo
Idioma:Inglês
Publicado em: 2010
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC3056320/
https://ncbi.nlm.nih.gov/pubmed/20831195
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja106593m
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