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Enantioselective Aldehyde α-Nitroalkylation via Oxidative Organocatalysis
[Image: see text] The first enantioselective organocatalytic α-nitroalkylation of aldehydes has been accomplished. The aforementioned process involves the oxidative coupling of an enamine intermediate, generated transiently via condensation of an amine catalyst with an aldehyde, with a silyl nitrona...
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| Main Authors: | , , |
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| Formato: | Artigo |
| Idioma: | Inglês |
| Publicado em: |
2009
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| Assuntos: | |
| Acesso em linha: | https://ncbi.nlm.nih.gov/pmc/articles/PMC3259685/ https://ncbi.nlm.nih.gov/pubmed/19627154 https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/ja904504j |
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