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The Photochemical Hexadehydro-Diels-Alder (hν-HDDA) Reaction

We demonstrate that the hexadehydro-Diels-Alder cycloisomerization reaction to produce reactive benzyne derivatives can be initiated photochemically. As with the thermal variant of the HDDA process, the reactive intermediates are formed in the absence of reagents or the resulting byproducts required...

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Bibliografske podrobnosti
izdano v:J Am Chem Soc
Main Authors: Xu, Feng, Xiao, Xiao, Hoye, Thomas R.
Format: Artigo
Jezik:Inglês
Izdano: 2017
Teme:
Online dostop:https://ncbi.nlm.nih.gov/pmc/articles/PMC6348472/
https://ncbi.nlm.nih.gov/pubmed/28548500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03832
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