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The Photochemical Hexadehydro-Diels-Alder (hν-HDDA) Reaction

We demonstrate that the hexadehydro-Diels-Alder cycloisomerization reaction to produce reactive benzyne derivatives can be initiated photochemically. As with the thermal variant of the HDDA process, the reactive intermediates are formed in the absence of reagents or the resulting byproducts required...

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Detalhes bibliográficos
Publicado no:J Am Chem Soc
Main Authors: Xu, Feng, Xiao, Xiao, Hoye, Thomas R.
Formato: Artigo
Idioma:Inglês
Publicado em: 2017
Assuntos:
Acesso em linha:https://ncbi.nlm.nih.gov/pmc/articles/PMC6348472/
https://ncbi.nlm.nih.gov/pubmed/28548500
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.7b03832
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