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Competition between classical and hexadehydro-Diels–Alder (HDDA) reactions of HDDA triynes with furan

We report here thermal reactions between furan and one of three related triyne substrates. Each triyne is capable of reacting initially in two modes: (i) unimolecular hexadehydro-Diels-Alder (HDDA) reaction or (ii) bimolecular Diels-Alder reaction between one of its alkynes with furan. The relative...

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Foilsithe in:Tetrahedron Lett
Main Authors: Nguyen, Quang Luu, Baire, Beeraiah, Hoye, Thomas R.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2014
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4443927/
https://ncbi.nlm.nih.gov/pubmed/26028780
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.12.053
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