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Competition between classical and hexadehydro-Diels–Alder (HDDA) reactions of HDDA triynes with furan

We report here thermal reactions between furan and one of three related triyne substrates. Each triyne is capable of reacting initially in two modes: (i) unimolecular hexadehydro-Diels-Alder (HDDA) reaction or (ii) bimolecular Diels-Alder reaction between one of its alkynes with furan. The relative...

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Bibliografische gegevens
Gepubliceerd in:Tetrahedron Lett
Hoofdauteurs: Nguyen, Quang Luu, Baire, Beeraiah, Hoye, Thomas R.
Formaat: Artigo
Taal:Inglês
Gepubliceerd in: 2014
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Online toegang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4443927/
https://ncbi.nlm.nih.gov/pubmed/26028780
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.12.053
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