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Competition between classical and hexadehydro-Diels–Alder (HDDA) reactions of HDDA triynes with furan

We report here thermal reactions between furan and one of three related triyne substrates. Each triyne is capable of reacting initially in two modes: (i) unimolecular hexadehydro-Diels-Alder (HDDA) reaction or (ii) bimolecular Diels-Alder reaction between one of its alkynes with furan. The relative...

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Veröffentlicht in:Tetrahedron Lett
Hauptverfasser: Nguyen, Quang Luu, Baire, Beeraiah, Hoye, Thomas R.
Format: Artigo
Sprache:Inglês
Veröffentlicht: 2014
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Online Zugang:https://ncbi.nlm.nih.gov/pmc/articles/PMC4443927/
https://ncbi.nlm.nih.gov/pubmed/26028780
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1016/j.tetlet.2014.12.053
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