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The aza-hexadehydro-Diels-Alder (aza-HDDA) reaction

The generation of pyridynes from diyne nitriles is reported. These cyano-containing precursors are analogs of the triyne substrates typically used for the hexadehydro-Diels-Alder (HDDA) cycloisomerization reactions that produce ring-fused benzynes. Hence, the new processes described represent aza-HD...

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Publicado en:J Am Chem Soc
Main Authors: Thompson, Severin K., Hoye, Thomas R.
Formato: Artigo
Idioma:Inglês
Publicado: 2019
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Acceso en liña:https://ncbi.nlm.nih.gov/pmc/articles/PMC6921493/
https://ncbi.nlm.nih.gov/pubmed/31789026
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.1021/jacs.9b11243
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