Lataa...

CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS–ALDER (HDDA) REACTION

Benzynes can be generated by the intramolecular thermal cycloisomerization of triynes–the title HDDA reaction. We report here that these can be trapped by cycloaddition reaction with trimethylsilyl azide (1,3-dipolar) or a furan or pyrrole (4+2 Diels–Alder).

Tallennettuna:
Bibliografiset tiedot
Päätekijät: Chen, Junhua, Baire, Beeraiah, Hoye, Thomas R.
Aineistotyyppi: Artigo
Kieli:Inglês
Julkaistu: 2013
Aiheet:
Linkit:https://ncbi.nlm.nih.gov/pmc/articles/PMC4045115/
https://ncbi.nlm.nih.gov/pubmed/24910496
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3987/COM-13-S(S)83
Tagit: Lisää tagi
Ei tageja, Lisää ensimmäinen tagi!