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CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS–ALDER (HDDA) REACTION

Benzynes can be generated by the intramolecular thermal cycloisomerization of triynes–the title HDDA reaction. We report here that these can be trapped by cycloaddition reaction with trimethylsilyl azide (1,3-dipolar) or a furan or pyrrole (4+2 Diels–Alder).

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書目詳細資料
Main Authors: Chen, Junhua, Baire, Beeraiah, Hoye, Thomas R.
格式: Artigo
語言:Inglês
出版: 2013
主題:
在線閱讀:https://ncbi.nlm.nih.gov/pmc/articles/PMC4045115/
https://ncbi.nlm.nih.gov/pubmed/24910496
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3987/COM-13-S(S)83
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