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CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS–ALDER (HDDA) REACTION

Benzynes can be generated by the intramolecular thermal cycloisomerization of triynes–the title HDDA reaction. We report here that these can be trapped by cycloaddition reaction with trimethylsilyl azide (1,3-dipolar) or a furan or pyrrole (4+2 Diels–Alder).

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Sonraí Bibleagrafaíochta
Main Authors: Chen, Junhua, Baire, Beeraiah, Hoye, Thomas R.
Formáid: Artigo
Teanga:Inglês
Foilsithe: 2013
Ábhair:
Rochtain Ar Líne:https://ncbi.nlm.nih.gov/pmc/articles/PMC4045115/
https://ncbi.nlm.nih.gov/pubmed/24910496
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3987/COM-13-S(S)83
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