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CYCLOADDITION REACTIONS OF AZIDE, FURAN, AND PYRROLE UNITS WITH BENZYNES GENERATED BY THE HEXADEHYDRO-DIELS–ALDER (HDDA) REACTION

Benzynes can be generated by the intramolecular thermal cycloisomerization of triynes–the title HDDA reaction. We report here that these can be trapped by cycloaddition reaction with trimethylsilyl azide (1,3-dipolar) or a furan or pyrrole (4+2 Diels–Alder).

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Bibliografiska uppgifter
Huvudupphovsmän: Chen, Junhua, Baire, Beeraiah, Hoye, Thomas R.
Materialtyp: Artigo
Språk:Inglês
Publicerad: 2013
Ämnen:
Länkar:https://ncbi.nlm.nih.gov/pmc/articles/PMC4045115/
https://ncbi.nlm.nih.gov/pubmed/24910496
https://ncbi.nlm.nih.govhttp://dx.doi.org/10.3987/COM-13-S(S)83
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